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Classification, Labelling and Safety Data Sheet of Hazardous Chemicals Regulations 2013

Key Information

Regulations to make further provisions for the classification, packaging, labelling, and safe handling of hazardous chemicals in the workplace to ensure the protection of persons and property at the workplace.

Source: DOSH - P.U. (A) 310

PART I - PRELIMINARY

Regulation 1. Citation and commencement

Regulation 2. Application

Regulation 3. Interpretation


PART II - CLASSIFICATION

Regulation 4. Duty of principal supplier to classify chemical as hazardous chemical

Regulation 5. Record of classification


PART III - PACKAGING

Regulation 6. Packaging requirement of hazardous chemical

Regulation 7. Seal of packaging


PART IV - LABELLING

Regulation 8. Duty to label packaging of hazardous chemical

Regulation 9. Requirement for hazard pictogram

Regulation 10. Rules of precedence for hazard pictograms and hazard statements on label

Regulation 11. Dimension of label

Regulation 12. Affixing and tagging of label


PART V - SAFETY DATA SHEET

Regulation 13. Duty to furnish Safety Data Sheet


PART VI - INVENTORY OF HAZARDOUS CHEMICALS

Regulation 14. Inventory of hazardous chemicals


PART VII - CONFIDENTIAL BUSINESS INFORMATION

Regulation 15. Confidential business information on hazardous chemical


PART VIII - REVOCATION

Regulation 16. Revocation


SCHEDULES

FIRST SCHEDULE [Regulation 3] - HAZARD CLASSIFICATION, HAZARD PICTOGRAM, SIGNAL WORD AND HAZARD STATEMENT

(a) Physical Hazards

Hazard ClassificationLabel Information
Hazard ClassHazard CategoryHazard PictogramSignal WordHazard Statement
Explosives
Unstable Explosives
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Danger
Unstable explosive
Division 1.1
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Danger
Explosive; mass explosion hazard
Division 1.2
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Danger
Explosive; severe projection hazard
Division 1.3
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Danger
Explosive; fire, blast or projection hazard
Division 1.4
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Warning
Fire or projection hazard
Division 1.5
Danger
May mass explode in fire
Division 1.6
Flammable gases
Category 1
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Danger
Extremely flammable gas
Category 2
Warning
Flammable gas
Flammable aerosols
Category 1
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Danger
Extremely flammable aerosol
Category 2
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Warning
Flammable aerosol
Flammable liquids
Category 1
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Danger
Extremely flammable liquid and vapour
Category 2
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Danger
Highly flammable liquid and vapour
Category 3
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Warning
Flammable liquid and vapour
Flammable solids
Category 1
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Danger
Flammable solid
Category 2
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Warning
Flammable solid
Oxidizing gases
Category 1
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Danger
May cause or intensify fire; oxidizer
Oxidizing liquids
Category 1
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Danger
May cause fire or explosion; strong oxidizer
Category 2
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Danger
May intensify fire; oxidizer
Category 3
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Warning
May intensify fire; oxidizer
Oxidizing solids
Category 1
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Danger
May cause fire or explosion; strong oxidizer
Category 2
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Danger
May intensify fire; oxidizer
Category 3
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Warning
May intensify fire; oxidizer
Gases under pressure
Compressed Gas
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Warning
Contains gas under pressure; may explode if heated
Liquefied Gas
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Warning
Contains gas under pressure; may explode if heated
Refrigerated Liquefied Gas
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Warning
Contains refrigerated gas; may cause cryogenic burns or injury
Dissolved Gas
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Warning
Contains gas under pressure; may explode if heated
Self-reactive chemicals
Type A
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Danger
Heating may cause explosion
Type B
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Danger
Heating may cause fire or explosion
Type C and D
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Danger
Heating may cause fire
Type E and F
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Warning
Heating may cause fire
Type G
Pyrophoric liquids
Category 1
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Danger
Catches fire spontaneously if exposed to air
Pyrophoric solids
Category 1
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Danger
Catches fire spontaneously if exposed to air
Self-heating chemicals
Category 1
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Danger
Self-heating; may catch fire
Category 2
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Warning
Self-heating in large quantities; may catch fire
Chemicals which, if in contact with water, emit flammable gases
Category 1
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Danger
If in contact with water, releases flammable gases which may ignite spontaneously
Category 2
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Danger
If in contact with water, releases flammable gases
Category 3
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Warning
If in contact with water, releases flammable gases
Organic peroxides
Type A
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Danger
Heating may cause explosion
Type B
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Danger
Heating may cause fire or explosion
Type C and D
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Danger
Heating may cause fire
Type E and F
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Warning
Heating may cause fire
Type G
Corrosive to metals
Category 1
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Warning
May be corrosive to metals

(b) Health Hazards

Hazard ClassificationLabel Information
Hazard ClassHazard CategoryHazard PictogramSignal WordHazard Statement
Acute toxicity (oral)
Category 1
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Danger
Fatal if swallowed
Category 2
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Danger
Fatal if swallowed
Category 3
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Danger
Toxic if swallowed
Category 4
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Warning
Harmful if swallowed
Acute toxicity (dermal)
Category 1
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Danger
Fatal if in contact with skin
Category 2
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Danger
Fatal if in contact with skin
Category 3
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Danger
Toxic if in contact with skin
Category 4
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Warning
Harmful if in contact with skin
Acute toxicity (inhalation)
Category 1
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Danger
Fatal if inhaled
Category 2
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Danger
Fatal if inhaled
Category 3
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Danger
Toxic if inhaled
Category 4
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Warning
Harmful if inhaled
Skin corrosion or irritation
Category 1A/1B/1C
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Danger
Causes severe skin burns and eye damage
Category 2
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Warning
Causes skin irritation
Serious eye damage or eye irritation
Category 1
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Danger
Causes serious eye damage
Category 2
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Warning
Causes serious eye irritation
Respiratory sensitization
Category 1
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Danger
May cause allergic or asthma symptoms or breathing difficulties if inhaled
Skin sensitization
Category 1
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Warning
May cause allergic skin reaction
Germ cell mutagenicity
Category 1A/1B
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Danger
May cause genetic defects

(state route of exposure, if it is conclusively proven that no other routes of exposure cause the hazard)
Category 2
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Warning
Suspected of causing genetic defects

(state route of exposure, if it is conclusively proven that no other routes of exposure cause the hazard)
Carcinogenicity
Category 1A/1B
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Danger
May cause cancer

(state route of exposure, if it is conclusively proven that no other routes of exposure cause the hazard)
Category 2
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Warning
Suspected of causing cancer

(state route of exposure, if it is conclusively proven that no other routes of exposure cause the hazard)
Reproductive toxicity
Category 1A/1B
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Danger
May damage fertility or the unborn child (state specific effect, if known)

(state route of exposure, if it is conclusively proven that no other routes of exposure cause the hazard)
Category 2
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Warning
Suspected of damaging fertility or the unborn child (state specific effect, if known)

(state route of exposure, if it is conclusively proven that no other routes of exposure cause the hazard)
Effects on or via lactation
-
-
May cause harm to breast-fed children
Specific target organ toxicity–single exposure
Category 1
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Danger
Causes damage to organs (state all organs affected, if known)

(state route of exposure, if it is conclusively proven that no other routes of exposure cause the hazard)
Category 2
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Warning
May cause damage to organs (state all organs affected, if known)

(state route of exposure, if it is conclusively proven that no other routes of exposure cause the hazard)
Category 3
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Warning
May cause respiratory irritation (respiratory tract irritation)

or

May cause drowsiness or dizziness (narcotic effects)
Specific target organ toxicity–repeated exposure
Category 1
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Danger
Causes damage to organs (state all organs affected, if known) through prolonged or repeated exposure

(state route of exposure, if it is conclusively proven that no other routes of exposure cause the hazard)
Category 2
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Warning
May cause damage to organs (state all organs affected, if known) through prolonged or repeated exposure

(state route of exposure, if it is conclusively proven that no other routes of exposure cause the hazard)
Aspiration hazard
Category 1
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Danger
May be fatal if swallowed and enters airways

(c) Environmental Hazards

Hazard ClassificationLabel Information
Hazard ClassHazard CategoryHazard PictogramSignal WordHazard Statement
Hazardous to the aquatic environment - acute hazard
Category 1
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Warning
Very toxic to aquatic life
Hazardous to the aquatic environment - chronic hazard
Category 1
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Warning
Very toxic to aquatic life with long lasting effects
Category 2
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Toxic to aquatic life with long lasting effects
Category 3
Category 4
May cause long lasting harmful effects to aquatic life
Hazardous to the ozone layer
Category 1
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Warning
Harms public health and the environment by destroying ozone in the upper atmosphere

SECOND SCHEDULE [Regulation 3] - HAZARD PICTOGRAMS

PictogramDescription
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Exploding bomb
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Flame
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Flame over circle
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Gas cylinder
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Corrosion
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Skull and crossbones
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Exclamation mark
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Health hazard
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Environment

THIRD SCHEDULE [Subregulation 8(6)] - COMBINED HAZARD STATEMENTS

FOURTH SCHEDULE [Regulation 11] - DIMENSION OF LABEL

Content of the PackagingDimension of Labels (in millimetres)
Not exceeding 3 litres
If practicable, at least 52 x 74
Greater than 3 litres but not exceeding 50 litres
At least 74 x 105
Greater than 50 litres but not exceeding 500 litres
At least 105 x 148
Greater than 500 litres
At least 148 x 210

FIFTH SCHEDULE [Regulation 13] - CUT-OFF VALUE OF CONCENTRATION

Hazard ClassCut-off Value
Acute toxicity
at 1.0% or more (≥ 1.0%)
Skin corrosion or irritation
at 1.0% or more (≥ 1.0%)
Serious eye damage or eye irritation
at 1.0% or more (≥ 1.0%)
Respiratory sensitization
at 0.1% or more (≥ 0.1%)
Skin sensitization
at 0.1% or more (≥ 0.1%)
Germ cell mutagenicity (Category 1)
at 0.1% or more (≥ 0.1%)
Germ cell mutagenicity (Category 2)
at 1.0% or more (≥ 1.0%)
Carcinogenic
at 0.1% or more (≥ 0.1%)
Reproductive toxicity
at 0.1% or more (≥ 0.1%)
Specific target organ toxicity - single exposure
at 1.0% or more (≥ 1.0%)
Specific target organ toxicity - repeated exposure
at 1.0% or more (≥ 1.0%)
Aspiration hazard
at 10.0% or more (≥ 10.0%)
Hazardous to the aquatic environment
at 1.0% or more (≥ 1.0%)
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